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Affichage des articles dont le libellé est News. Afficher tous les articles
Affichage des articles dont le libellé est News. Afficher tous les articles

mercredi 13 avril 2016

“Worlds Brightest” Military Grade Flashlight Now Available To Public


“Worlds Brightest” Military Grade Flashlight Now Available To Public

You know how after someone takes a picture of you at night with the flash on, it takes like 3 minutes to see properly again?
Now imagine that flash is 100x brighter and it doesn’t turn off. You’d have the ability to disorient any would be attacker with the push of a button.
That’s what you get with the LumiTact G700 – a new Military Grade tactical flashlight.
The truth is, most people underestimate the importance of owning a great flashlight. And these days, in a world where terrorism, and natural disasters are becoming the norm, it’s more important than ever to have the right tactical gear.
This light’s incredible LED technology is used by the U.S. Navy Seals, the Coast Guard, Firemen, Policemen, U.S. Search and Rescue and now it’s been placed inside of an amazing Flashlight called the LumiTact G700…

“In times like these, it’s more important than ever for Americans to be prepared for anything, and this flashlight is one of the best pieces of gear to have as it can be used in almost every situation, from self defense to finding your dog at night…” -Matt B. Tactical Flashlight Expert

With Over 20,000 Sold This Month, People Are Talking:



3


 






“I can’t believe they’re giving this light away for 75% off”

These $200 lights are currently selling for 75% off their normal price! So make sure you hurry and grab yours now at the discounted price.
So if you want to make sure you’re always prepared for the worst, this flashlight is a great start. It has our vote
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Russian TV spy claims shown up by poor English

Russian TV spy claims shown up by poor English


Russian state TV has accused a leading Kremlin critic of being an agent for the British and US intelligence services. But its accusations are based on documents that are full of grammatical errors and have been branded as forgeries.
On Sunday night, official channel Rossiya 1 ran a 15-minute report alleging that anti-corruption campaigner Alexei Navalny had been working for many years as an "agent" for MI6.
Controversial TV anchor Dmitry Kiselyov described the allegations as "sensational" and stressed that some of Mr Navalny's actions had been "criminal".
Following his emergence as arguably President Vladimir Putin's most formidable opponent, Mr Navalny has twice been convicted on charges of embezzlement in trials that he and his supporters say were politically motivated.
Two suspended prison sentences have left him sidelined from electoral politics.
The Rossiya 1 report suggested that Mr Navalny had been recruited to work for MI6 by UK hedge fund manager Bill Browder some time between 2006 and 2008.
The report went on to allege that he had been paid handsomely for his services via the Moscow Helsinki Group (MHG) human rights organisation.
His anti-corruption activities, including his recent allegations against the family of Russian Prosecutor-General Yuri Chaika, were also presented as being part of a CIA operation codenamed "Quake".
Mr Navalny has dismissed the accusations as "fantasy" and "deliberate slander" and has said he will sue the state broadcaster.
MHG head Lyudmila Alekseyeva said the group had never given money to Mr Navalny.

Image copyright Rossiya 1
Image caption Alleged Skype correspondence between Navalny and UK hedge fund manager Bill Browder
As evidence for its accusations, Rossiya 1 reporter Yevgeny Popov quoted what he said was Skype correspondence between Mr Navalny and Mr Browder, as well as a number of purported MI6 and CIA internal documents, which were shown on screen with Russian translations.
The documents referred to Mr Navalny as agent "Freedom" and Mr Browder as "Solomon".
Bill Browder was the inspiration behind the US Magnitsky Act, under which sanctions were imposed on Russian officials said to be complicit in the death of Sergei Magnitsky in Russian custody. Mr Magnitsky had been working for Mr Browder's company, Hermitage Capital.
The TV report suggested Mr Browder had himself conspired with the CIA to bring about Mr Magnitsky's death.

English errors

But the documents on which this and the other accusations are based have roused suspicion, not least because they contain mistakes in English commonly made by Russian speakers.
"Navalny is the most suitable candidate for the future political leader," reads one.
Another says funds "will be transferred to our trustee from Moscow Helsinki Group until January 26th". Such incorrect use of "until" instead of "by" is common among Russian speakers.

Image copyright Rossiya 1
Image caption Documents shown by Rossiya 1 contained a number of common Russian mistakes in English
One reference to Mr Putin in January 2008 as the "acting president of the Russian Federation" appears to be another mistranslation from the Russian, where in English the word "serving" or "current" would be expected.
And it is not just the language at fault.
Some social media users pointed out that the name on the bottom of an alleged CIA document dated 2009 appears to be that of Valerie Plame, whose career in the service was over more than three years earlier.
This is not the first time Russian media have been apparently caught peddling fake documents. Last November, pro-Putin newspaper Izvestia printed a similarly error-strewn letter that it claimed was from a US state department official to a Russian LGBT activist.

Image copyright US embassy Moscow
Image caption Last November the US embassy poked fun at an Izvestia forgery, suggesting it would be happy to correct future mistakes


Image copyright Getty Images
Image caption The 2006 spy rock affair involved alleged British agents in Moscow
Russian state TV has a long history of alleging links between Kremlin critics and foreign powers. The most famous was the so-called "spy rock" affair in 2006, which focused on the activities of alleged British secret agents.

"Information war"

Writing on liberal website Slon.ru, well-known journalist Oleg Kashin said Mr Popov's report was based on an "indecent fake".
He also suggested it was a product of the "information war" the Kremlin believed it was waging with the West.
The allegations against Navalny came exactly a week after the release of the Panama Papers, which appear to reveal suspicious offshore transactions involving members of the Russian president's inner circle.
Russian state TV initially ignored these revelations, but later branded them part of a US-inspired plot to destabilise Mr Putin.
Rossiya 1 has said that it will air a fuller version of Mr Popov's report in a late-night talk show on Wednesday.
But, despite the sensational nature of the allegations against Mr Navalny, pro-Kremlin media do not appear anxious to publicise them further.
They did not appear in any of the main TV bulletins on Monday evening. Nor did they feature in the Monday or Tuesday print editions of the top pro-Kremlin newspapers.
BBC Monitoring reports and analyses news from TV, radio, web and print media around the world. You can follow BBC Monitoring on Twitter and Facebook.

Related Topics

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Ted Cruz: New Jersey judge rejects US citizenship challenge

Ted Cruz: New Jersey judge rejects US citizenship challenge


A judge in New Jersey has ruled that Republican presidential hopeful Ted Cruz is a "natural-born citizen" under the US constitution and may run in the state's primary elections in June.
A group of residents had challenged the Texas senator's eligibility for the presidency. He was born in Canada to a Cuban father and American mother.
But Judge Jeff Masin found that Mr Cruz met the constitutional requirements.
New Jersey's Lt Governor, Kim Guadagno, is now expected to review the decision.
Sen Cruz's main rival for the Republican nomination, Donald Trump, has also questioned his eligibility for the presidency.
"There's a big question mark on your head," the billionaire businessman said at a debate in January. "You can't do that to the party."

'No absolute certainty'

The South Jersey Concerned Citizens Committee and law professor Victor Williams, a presidential write-in candidate, argued in court in on Monday that Sen Cruz's birth in Canada meant he could not be a "natural-born citizen" as envisaged by those who wrote the US constitution.
They claimed he was a naturalised citizen and that presidents had to be born on US soil.
Sen Cruz's lawyer argued that he was a natural-born citizen because his mother was American.
On Tuesday, Judge Masin dismissed the challenge, while acknowledging that "absolute certainty as to this issue is only available to those who actually sat in Philadelphia and themselves thought on the issue".
"The more persuasive legal analysis is that such a child, born of a citizen-father, citizen-mother, or both, is indeed a 'natural born citizen' within the contemplation of the constitution," he wrote in a 26-page decision.
Judge Masin added that his decision might be adopted, modified or rejected by Lt Gov Guadagno, New Jersey's secretary of state, who is authorised to make a final decision on the matter. She must transmit the names of candidates to appear on the primary ballot to county clerks by Thursday.
A similar legal challenge was rejected a court in Pennsylvania, where Sen Cruz will appear on the state's Republican primary ballot later this month.
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Brazil coalition partners 'to vote for Rousseff impeachment

Brazil coalition partners 'to vote for Rousseff impeachment'



Two former coalition partners of Brazil President Dilma Rousseff say they will vote for her impeachment over claims she manipulated government accounts.
The Progressive Party (PP), which quit the coalition on Tuesday, says most of its 47 MPs would vote for the impeachment.
The Republican Party (PRB) said its 22 members had been told to vote for it.
The move comes weeks after the PMDB, the largest party in the the lower house, voted to leave the coalition.
Ms Rousseff says her opponents are plotting a "coup".
She faces an impeachment vote in the lower house on Sunday, amid claims she juggled the accounts to make her government's economic performance appear better than it was ahead of her election campaign two years ago.
She denies the allegations, and her supporters say the issue is not valid grounds for impeachment anyway.
A PP spokeswoman told AFP news agency on Tuesday: "The party decided to withdraw from the... alliance, by majority decision." The PP is the fourth-largest party in the 513-seat lower house.
Hours later, the leadership of the PRB confirmed to BBC Brasil that its members had been told to support the removal of the president or face sanctions, including possible expulsion.
While the two developments weaken the position of the president ahead of the impeachment vote, its outcome is uncertain with many members of the lower house still undecided.
A two-thirds majority - 342 MPs - is needed to send the impeachment case to the Senate.
A recent poll, before the PP's announcement, showed 300 in favour of impeachment and 125 opposed, leaving 88 MPs still undecided or not stating their position.




You need to install Flash Player to play this content.
Media captionBrazil political crisis: Why Dilma Rousseff faces impeachment calls
Earlier on Tuesday, Ms Rousseff suggested that her Vice-President Michel Temer was one of the ringleaders of the "coup" attempt against her.
She said a widely distributed audio message of Mr Temer appearing to accept replacing her as president, was evidence of the conspiracy. However, she did not identify him by name.
"They now are conspiring openly, in the light of day, to destabilise a legitimately elected president," Ms Rousseff said.
She referred to "the chief and... the vice-chief" of the plot, an apparent reference to Mr Temer and lower house speaker Eduardo Cunha.
Brazil is "living in strange times", she said, "times of a coup, of farce and betrayal".
Mr Temer has said that the message was released by accident.


Image copyright Reuters
Image caption President Rousseff denies the accusations against her
Speaking in an interview with the conservative Estado de Sao Paulo newspaper on Tuesday, Mr Temer argued that he had spent weeks away from the capital Brasilia specifically so that no-one could accuse him of plotting behind the scenes.
On Monday evening, amid rowdy scenes, a 65-member congressional committee voted 38 to 27 to recommend going ahead with impeachment proceedings.
MPs are due to start debating on Friday, officials said, with voting beginning on Sunday at about 14:00 (17:00 GMT). The result should be known later in the evening.
Security is expected to be stepped up around the Congress building in Brasilia as the vote takes place.
While President Rousseff's opponents say the impeachment is supported by most Brazilians, the president's supporters have labelled it a flagrant power grab by her political enemies.
If the president and Mr Temer are both suspended from office, the next in line to assume the presidency is Mr Cunha.
However, he is facing money-laundering and other charges.



Where did it go wrong? Daniel Gallas, Sao Paulo


From billions being stolen from state oil giant Petrobras by private construction firms and politicians, to a powerful senator negotiating for a key witness to flee from jail, the country has been rife with jaw-dropping corruption revelations.
Yet with all the investigations, one person has managed to keep a fairly clean record - President Dilma Rousseff.
Ms Rousseff's personal record on corruption may be untarnished so far - but her handling of the economy has been highly controversial. And this is the argument the opposition has been advancing to get her impeached.
Making what critics say are bad decisions on the economy is not a crime. But one of the measures taken by Ms Rousseff and her team back in 2014 was deemed illegal by a federal court.
Brazilian governments are required to meet budget surplus targets set in Congress. Ms Rousseff is accused of allowing creative accounting techniques involving loans from public banks to the treasury that artificially enhanced the budget surplus.
Read the full article here



Rousseff under pressure

The Brazilian president faces a battle to stay in power

  • 513 members of the lower house of Congress
  • 342 votes needed to move process to the Senate
  • 41 senators out of 81 must vote in favour to begin impeachment trial
  • 180 days she could be suspended for during the hearings
Reuters



What happens next?

Lower house vote: An impeachment vote is expected in the lower house on Sunday. A two-thirds majority is required for it to go forward to the Senate. Latest surveys suggest the number in favour is short of the total needed to carry the motion.
Senate vote on trial: If Ms Rousseff case is sent to the Senate, a simple majority is enough to suspend her for up to 180 days while she is put on trial. Vice-President Michel Temer would step in during this period.
Impeachment vote: For Ms Rousseff to be removed from office permanently, two-thirds of the Senate would have to vote in favour. Mr Temer would remain president for an interim period should this happen.


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mardi 12 avril 2016

Medical Council Should Implement High Court Verdict: Delhi Medical Association

Medical Council Should Implement High Court Verdict: Delhi Medical Association

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Medical Council Should Implement High Court Verdict: Delhi Medical Association
Delhi High Court had last week ruled that the practitioners of 'Bharatiya Chikitsa' - Indian System of Medicine - such as Ayurveda, Siddha, Tibb and Unani medicine cannot practise scientific system of medicine. (Representational Image)
New Delhi:  Delhi Medical Association today demanded that the Medical Council of India (MCI) implement the High Court order barring Ayurveda and Unani medicine doctors to practice allopathy.

Delhi High Court had last week ruled that the practitioners of 'Bharatiya Chikitsa' - Indian System of Medicine - such as Ayurveda, Siddha, Tibb and Unani medicine cannot practise modern scientific system of medicine including prescribing allopathic medicines.

Delhi Medical Association (DMA), which is an association of registered medical practitioners of Allopathic System of Medicine affiliated to the Indian Medical Association (IMA), had filed a petition before the HC saying practitioners of 'Bharatiya Chikitsa' in the capital were prescribing allopathic drugs, jeopardizing the health of residents of the city.

"We welcome the High Court judgement and demand that the Delhi Medical Council (DMC) and Medical Council of India (MCI) to take strict action against those violating the court's order and restrict the 'Bharatiya Chikitsa' doctors to practice modern medicine," DMA President Rakesh Gupta told reporters.

"It is important to check the business run by quacks in various areas of Delhi. We urge MCI and DMC to conduct frequent raids and file police complaints against the defaulters," he added.
 
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lundi 11 avril 2016

ebay easy way to earn money

Learn smart new way to win at ebay important sums of money every month by selling products they do not own and easily site.


 There are plenty of ways to make money Heb Internet, but in this post you will learn one of the most ways that generate easy money and effort is simple, through the sale of products does not already own on eBay rich platform for easily definition, and reap a respectable amount of money, the you are intelligent and you sell a great good products so be sure that you will be able to achieve significant amounts of money per day, depending on the products taken it from other shopping sites and placed in the site ebay, and the way Snscherhaa in detail in this post:



As a preliminary observation of the profit from the sale of products must be available on the money I would not say $ 100, but any amount will be able to start racing him even though it was only $ 5.
For the method of selling products that are not owned on eBay and profit sums it very easy, is sufficient for you look for a good commodity in other shopping sites exampleThis site or this and then put it on eBay the same platform, it is important not to dwell too long then go to the eBay site and create an account after the account creation and login information follow me, and everything just change the price of the commodity in order to win money from them.


  Click to sell it myself
 Now you will see another interface then take the information to your chosen product, and placing them in front as I put it as only change the price for any price you want:



 As you can see it has been selling successfully but my remark would not be able to use the funds obtained only after 20 days because you're a new seller but over time you will get your money the same day.
As you can see it has been selling successfully but my remark would not be able to use the funds obtained only after 20 days because you're a new seller but over time you will get your money the same day.
It is explicitly a great way to make money has been advised by a friend who bring them a very good amount and I would recommend it to search for shopping sites that sell cheap goods.
 
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dimanche 10 avril 2016

This vedio can explain to you how you can earn money for free

This vedio can explain to you how you can earn money for free :

That's the link :Click here
 


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Regarder Divergente 3 : au-delà du mur en streaming

Regarder Divergente 3 : au-delà du mur en streaming

Regarder Divergente 3 : au-delà du mur en streaming

 

Film Divergente 3 : au-delà du mur complet streaming

Adaptation de la suite de « Divergente » et « Insurgent », 1e partie.

Les Lecteurs : Divergente 3 : au-delà du mur gratuit en illimité

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How to get word for free in windows 10

   
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It's a common misconception that Windows comes complete with Microsoft Office for every user. However, there are ways of getting Office, including Word, on Windows 10 for free.
So you've got a new Windows 10 PC, laptop or tablet and want to use Microsoft Office but can't afford to buy it. Well luckily, there are ways of getting Office for free (restrictions apply) and we're going to show you how.
See also: How to get Office 2016 for less than £10.

How to get Office for free on Windows 10 including Word and Excel

Microsoft's current strategy for Office means that you can download its mobile apps for Word, Excel, and PowerPoint for free on a wide range of devices including Android and iOS. You can download these apps for Windows 10 using the links below.
•    Word Mobile
•    Excel Mobile
•    PowerPoint Mobile
Office Mobile Windows store

What you can and can't do

While these are free for any Windows 10 device, they don't simply allow you full access to all the functionality. If you're using a PC or laptop you'll only be able to read documents and will need an Office 365 subscription to create and edit. However, those of you running Windows 10 on a device with a 10.1in screen or smaller can use the apps fully including creating and editing.
Being able to view documents is pretty basic so for anyone on a PC, laptop or tablet with a screen bigger than 10.1in then you'll want to use an alternative to Microsoft Office if you don't want to pay. An Office 365 Subscription will cost you from £5.99 per month.
Before we look at some alternatives, remember that you can use Office Online if you have a Microsoft account. This is essentially Office but you just use it entirely in your web browser. You can also try Office 2016 for free.

Best free Microsoft Office alternatives

There are various alternatives to Microsoft Office out there that are completely free. Our recommendation is LibreOffice, which is a full suite of software and allows you to open and save documents in Microsoft formats. Download LibreOffice here.
Should you happen to dislike Libre Office, you can also check out free alternatives such as WPS Office, Free Office and Google Docs which is now simple a part of Google Drive.
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Fais ft. Afrojack - Hey (Official Video)

          
   

      That's me when I was a child hhhh
  
  Here the link :HEY
 
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samedi 9 avril 2016

Propeller Ads Review

Propeller Ads Review: Pros & Cons And Everything You Need To Know

Google AdSense is the biggest (and the most popular) ad network with millions of advertisers and publishers. Thanks to Google’s huge AdWords ad inventory.
However, it doesn’t really mean that AdSense is always the best way to monetize your website. There are a dozen other ad networks that are willing to pay a higher CPM for your traffic. Propeller Ads is one of them.
CPM (Cost Per Mille) stands for Cost Per 1,000 Impressions. CPM networks pays for every 1,000 impressions you generate. If a CPM ad network is paying you $1 CPM then it means that they’re paying you $1 for every 1,000 page views you generate.
Over the past one decade I’ve recommended AdSense and only AdSense — on my blog posts, blog comments, email enquiries, and everywhere else. And it was simply because… AdSense has got an ad inventory that’s unmatched by any other ad network. So, I imagined that no other ad network can beat the CPM offered by AdSense.
But the problem is… we can’t predict the AdSense income. As you can see… I’m not longer monetizing the blog with any of those ad networks and the reason is none of them gives guaranteed income (except private ads network like BuySellAds.com).
I used to average around $0.50 per click on AdSense for several years and then it suddenly dropped to $0.05-$0.15 per click for few months and then it started giving over $1 per click. However, it didn’t last for long and I pulled off all sorts of ad networks on the blog and started selling selective private ads only.

Why Propeller Ads

Propeller Ads
Propeller Ads is an ad network based in U.K. that promises 100% of your international traffic and the highest CPM possible. Traffic from the following countries generates the maximum CPM: U.S. & Canada, U.K., and Australia.
Unlike Google AdSense, Propeller Ads is a CPM ad network which basically means that it pays for every 1,000 ad impressions you generate. So it doesn’t matter whether the users are clicking your ads or not — you get paid! And that’s why large publishers prefer CPM networks over CPC ad networks (like AdSense, Bing Ads, etc.).
If your traffic and its quality is stable then CPM ads can generate guaranteed income every day and every month. Have you ever noticed the way some of the high-traffic websites display content as 10-50 slides? Yes, it’s to increase the number of pages views per visit — and eventually the CPM.

Propeller Ads: Types Of Ad Products

Propeller Ads offers you a variety of ad products and that’s one space where Propeller Ads outsmart other ad networks — including Google AdSense. So it doesn’t matter what type of your blog or website you own — there will always be an ad product for you.
But that doesn’t mean that you can send them fake traffic (autosurf, traffic exchanges, etc.) and make a lot of money. It won’t work that way. Obviously.
Here are the different types of ad products offered by Propeller Ads:

1. OnClick PopUnder Ads

OnClick PopUnder Ads is perhaps the most effective ad product by Propeller Ads as it offers the maximum CPM rate (up to $10). It’s because you get paid for each ad impression (it works on mobile devices too!).
According to Propeller Ads, entertainment websites (music, movies, photo, downloads, games, viral content, etc.) gets the best CPM for pop-under ads.
Here is what can you expect from a:
Gaming Website
Gaming Website
Viral Blog
Viral Blog

2. Mobile Ads

Propeller Ads offers two types of mobile ads: Mobile Dialog Ads and Mobile Interstitial Ads (apart from the regular mobile banner ads).
Here is what can you expect from a:
Music Website
Music Website
Mobile Dialog Ads
Dialog Ads is a kind of an alert that show users as a dialogue box. So it’s almost certain to attract  user’s attention and that should result in higher click-through-rate and thereby CPM.
Here is what can you expect from a:
Music Website
Music Website  — With most of the traffic from India
Mobile Interstitial Ads
Mobile Interstitial Ads is a full screen mobile ad. It’s one of the top performing ad product by Propeller Ads because of its higher user engagement.
Here is what can you expect from a:
Entertainment Blog
Entertainment Blog

3. Classic Banner Ads

Banner ads are still popular as it’s the easiest way to reach out to a massive audience at minimal costs. The best performing banner ads by Propeller Ads are ad units of sizes: 300×250 and 728×90. Other available ad units are: 468×60, 120×600, 160×600, 800×600, 800×440, and 320×50.
You can check out their best practices for banner ads placement here. According to Propeller Ads, entertainment blogs and download sites tends to perform better than other niche.
Here is what can you expect from a:
Movie WebsiteMovie Website

Mobile Apps Review Website
Mobile Apps Review Website
Gaming Blog
Gaming Blog

4. Layer Ads

Layer Ad is a banner ad on steroid as it loads banner ads over the website content. You can choose any of the available banner ad units but a bigger ad unit such as 800×600 or 800×440 is recommended.

5. Slider Ads

Slider Ad is again another kind of banner ad that fades in at the bottom of a web page. Unless the user decides to close, it’s always visible even if he/she is scrolling up or down.

6. Direct Ads

Direct Ads (or Direct Links) is a unique ad product in which publishers are given a URL to promote. You can promote it by creating your own banner ads, text link ads, buttons, or even redirects.
For instance, you can monetize your 404 pages with a direct ad — without hurting user experience. According to Propeller Ads, it works best on a downloads website (ebooks, music, apps, wallpapers, movies, etc.)
Here is what can you expect from a:
File Sharing Website
File Sharing Website
Video Sharing Website
Video Sharing Website

7. Video Ads

If you want to monetize your video content then can try Video Ads. Propeller Ads offers three video ad spots: Pre-Roll, Mid-Roll, Post-Roll, and Pre-Game.
Note: All the earning screenshots are collected as part of the research (with majority of them shared by Propeller Ads itself on request). I do not run Propeller Ads on my blog as I prefer selling private ads only. I’ve included as much screenshots as I can — from different industires — so that you can use it as a benchmark to find out whether your earnings are on par with other publishers.

Propeller Ads: Pros & Cons

First things first. Propeller Ads is not exactly an AdSense alternative. Google AdSense is a pay-per-click ad network and Propeller Ads is a CPM ad network. It basically means, AdSense pays for each click-throughs from your website and Propeller Ads pays for every 1,000 ad impressions.
Google AdSense works best when your website is in a competitive niche with majority of traffic from organic search (that is, from search engines). If you have a high traffic website that’s in a non-competitive industry then the AdSense earnings could be terrible (especially when its organic traffic is less).
Again, AdSense is a good choice for file sharing websites, forums, downloads websites where the traffic quality is low but the page views/visits ratio is very high. Luckily Propeller Ads (and similar banner networks) works very well on such websites.

Pros

  • It’s super easy to get started as all accounts are activated instantly. You can login to your publisher account and add all the domain names that you wish to monetize and you will be notified via email when it’s approved.
  • Propeller Ads share 80% of their ad revenue with publishers. But it’s not a good idea to compare two advertisers based only on their revenue sharing percentage as we don’t know the real size of their total ad inventory. An advertiser with a massive ad inventory can easily beat the CPM of a small ad network with just 50% revenue sharing.
  • The reporting of Propeller Ads is pretty simple. It shows your earnings in a tabular way or on a chart. And the best thing? It’s real-time!
  • Propeller Ads supports the following payment methods: Wire Transfer, Payoneer, Webmoney, and Prepaid Cards. The minimum payment amount will be $500 for Wire Transfers and $100 for all other payment methods and is based on a NET 30 terms. That is, if your total earnings at the end of January is $300 then you will be paid in the first week of March.
  • Propeller Ads accepts all websites irrespective of their traffic as long as it doesn’t violate their terms and conditions.
  • It generates the maximum CPM for entertainment websites (including downloads, music, movies, viral blogs, etc.).
  • As a publisher you can refer other publishers to Propeller Ads and can earn 5% of his/her future ad revenue — for lifetime.
  • You can even monetize your 404 pages with a full-screen ad. No more wasted traffic!
  • You can run Propeller Ads along with ads from other advertising or affiliate networks — like AdSense, Infolinks, CJ, etc.
  • If you are a new publisher and is looking for some personal assistance then you get direct one-to-one support via email or Skype. Also, if you have a high traffic website then you get a dedicated account manager who will assist you to optimize the traffic.

Cons

  • Poor user experience. Your visitors may find full-screen ads, pop-under ads, push ads, etc. as annoying.
  • Do not support PayPal payments. It’s really a big turn off because even almost all top AdSense alternatives support PayPal.
  • Once again, the minimum payout is also on the higher side. And I suppose it’s because they do not support PayPal payments.
  • The best performing ad units are not traditional banner ads or mobile ads — it’s pop-under ads and full-page ads. But users (including me) hate it. However, if you have a high traffic file sharing website or a downloads website or a maybe even a forum then pop-under ads could be the right choice.
  • It’s true that Propeller Ads is accepting all sorts of publisher websites (unless of course it doesn’t comply with their terms and conditions) but it appears like if you want to generate handsome income then you need either a high-traffic website or a website with high-quality traffic.
  • If your traffic quality is low (it means you get few traffic from U.S., U.K., and Europe) then Propeller Ads may not be a right choice unless you want to try pop-under ads, full-page ads, etc.
  • Again, Propeller Ads considers conversions as well when calculating CPM. A CPM network is supposed to pay a fixed income for every 1,000 pages views irrespective of conversions. But Propeller Ads offers more payment models to advertisers like — CPC (Cost Per Click) and CPA (Cost Per Action). So your final earnings depends upon the type of ad inventory too.
  • Your CPM could be extremely low if the traffic quality is poor. Of course, AdSense also do not pay much for low quality traffic but at Propeller Ads it’s much more worse. Here’s a screenshot of a popular Spanish tech blog that receives no meaningful traffic from English speaking countries. Its CPM with Google AdSense was around $0.20 but as you can see Propeller Ads’ banner ads are not even generating a CPM of $0.05.
Spanish Tech Blog
Conclusion
Propeller Ads is not another network where you could fake traffic and money. Like AdSense or any other reliable publisher network — you need real traffic to make real income.
Google AdSense do not accept all publisher websites (especially new ones) as they have  strict guidelines. In fact, publisher websites are required to comply with Google’s AdSense Guidelines as well as the Webmaster Guidelines. It basically means if you’re doing black hat SEO or is selling text links on your website then they can disable your AdSense account.
So should you consider Propeller Ads over Google AdSense? Well, it depends. If your website (or blog) is new then there’s every chance that Google will deny your AdSense application and you can consider Propeller Ads.
Again, if you have a small or large website that’s already running AdSense ads but is not making enough — even though majority of your traffic is from English speaking nations — then it makes sense to give Propeller Ads a try.
Or, it’s a good idea to supplement your existing AdSense income with pop-under ads by Propeller Ads (as it offers the maximum CPM). Just make sure that your users won’t be annoyed about it.
Happy Monetizing! :)
Disclosure: This review was sponsored (?) by Propeller Ads. However, it hasn’t influenced my views in any way as they paid for my time and not for a biased positive review.
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vendredi 8 avril 2016

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réaction chimique : avancement

réaction chimique : avancement
Avancement d'une réaction chimique :Equation : aA + bB = cC + dD (A, B : réactifs ; C, D : produits )
x (mol) : avancement de la réaction
n(A)0 : quantité de matière initiale (mol) de A
n(A) : quantité de matière (mol) de A à la date t
n(A)f : quantité de matière finale (mol) de A
Tableau d'avancement ou tableau d'évolution de la réaction :
équation chimique
a A
b B
c C
d D
état du système
avancement
quantité de matière (mol)
état initial
0
n(A)0
n(B)0
0
0
en cours de transformation
x
n(A)0 - a x
n(B)0 - b x
c x
d x
état final
xf
n(A)0 - a xf
n(B)0 - b xf
c xf
d xf


1propane
Soit la combustion complète du propane C3H8 dans le dioxygène donnant du dioxyde de carbone et de l'eau.
  1. Ecrire l'équation de cette réaction en utilisant les nombres stoechiométriques entiers les plus petits possibles
  2. Préparer des tableaux d'évolution pour les 2 systèmes ci dessous
  • le premier correspond à un état initial constitué de 2 mol de propane et de 7 mol de dioxygène; déterminer l'état final du système
  • le second correspond à un état initial constitué de 1,5 mol de propane et de 7,5 mol de dioxygène; déterminer l'état final du système et conclure.  

corrigé
C3H8 + 5 O2 donne 3 CO2 + 4 H2O
propane
dioxygène
dioxyde de carbone
eau
initial t=0
2 mol
7 mol
0
0
en cours
2-x
7-5x
x
x
final
2-1,4 = 0,6 mol
0
3*1,4 = 4,2 mol
4*1,4 =5,6 mol
avancement maximal : l'un au moins des réactifs a disparu
soit 2-x =0 --> x=2 mol
soit 7-5x = 0 --> x=1,4 mol
on retient la plus petite valeur: elle correspond à l'avancement maximal
Le propane est en excès et la réaction s'arrète lorsque tout le dioxygène est consommé.
la composition finale du mélange est donnée par la dernière ligne du tableau.

propane
dioxygène
dioxyde de carbone
eau
initial t=0
1,5 mol
7 ,5mol
0
0
en cours
1,5-x
7,5-5x
x
x
final
0
0
3*1,5 = 4,5 mol
4*1,5 = 6 mol

avancement maximal : l'un au moins des réactifs a disparu
soit 1,5-x =0 --> x=1,5 mol
soit 7,5-5x = 0 --> x=1,5 mol
valeur identique: elle correspond à l'avancement maximal
Le propane est le dioxygène sont en proportions stoéchiomètriques


2soufre

L'une des étapes de la synthèse de l'acide sulfurique est la réaction entre le sulfure d'hydrogène H2S et le dioxyde de soufre SO2. Le soufre S et l'eau sont les produits de cette réactiion.
  1. Ecrire l'équation de cette réaction en utilisant les nombres stoechiométriques entiers les plus petits possibles
  2. Préparer un tableau d'évolution pour le système suivant : 4 mol SO2 et 5 mol H2S. Déterminer l'avancement maximal et le réactif limitant.
  3. Quelle est la composition molaire de l'état final.
  4. On considère maintenant le mélange initial suivant : 3,5 mol SO2 et n mol H2S. Déterminer n pour que le mélange soit stoéchiométrique; en déduire l'état final

corrigé
2 H2S + SO2 donne 3 S + H2O
H2S
SO2
soufre
eau
initial t=0
5 mol
4 mol
0
0
en cours
5-2 x
4 - x
x
x
final
0
4-2,5 = 1,5 mol
3*2,5 = 7,5 mol
2*2,5 =5 mol
avancement maximal : l'un au moins des réactifs a disparu
soit 5-2x =0 --> x=2,5 mol
soit 4-x = 0 --> x=4 mol
on retient la plus petite valeur: elle correspond à l'avancement maximal
SO2 est en excès et la réaction s'arrète lorsque tout H2S est consommé.
la composition finale du mélange est donnée par la dernière ligne du tableau.

H2S
SO2
soufre
eau
initial t=0
n mol
3,5 mol
0
0
en cours
n-2 x
3,5 - x
x
x
final
0
0
3*2,5 = 7,5 mol
2*2,5 =5 mol
avancement maximal : les deux réactifs ont disparu ( conditions stoéchiomètriques)
soit 3,5-x =0 --> x=3,5 mol
et n-2 x = 0 --> n =2x = 7 mol


3éthanol
On considère la combustion complète de l'éthanol C2H6O dans le dioxygène. Les seuls produits sont le dioxyde de carbone et l'eau.
  1. Ecrire l'équation de cette réaction en utilisant les nombres stoechiométriques entiers les plus petits possibles
  2. Dans une première expérience on fait brûler n=0,2 mol d'éthanol. Déterminer :
    la quantité minimale de dioxygène correspondant à cette combustion complète.
    les quantités de matière puis la masse de chacun des produits obtenus (C=12 ; H=1 ; O= 16 g/mol)
    le volume de dioxygène consommé ( volume molaire = 25 L/mol)
  3. Une nouvelle expérience met en jeu une masse m= 2,3 g d'éthanol et un volume V=1,5 L de dioxygène. Après avoir déterminé les quantités de matière (mol) des réactifs présents initialement déterminer :
    l'avancement maximal de la réaction et le réactif limitant
    la composition en mol de l'état final du système.

corrigé
C2H6O + 3 O2 donne 2 CO2 + 3 H2Oles quantités de matière (mol) des réactifs initiaux sont stoéchiométriques.
à partir de 0,2 mol d'éthanol, *0,2 = 0,6 mol de dioxygène sont nécessaires.
On obtient alors : *0,2 = 0,4 mol CO2 et 3 *0,2 = 0,6 mol H2O
soit en masse : 0,4*(12+16*2) = 17,6 g CO2 et 0,6 (2+16) = 10,8 g d'eau.
volume de dioxygène : 0,6 * 25 = 15 L

Quantités initiales des réactifs :
alcool ( masse molaire : 2*12+6+16 )= 46 g/mol) : 2,3 /46 = 0,05 mol
dioxygène : 1,5 / 25 = 0,06 mol
C2H6O
O2
CO2
eau
initial t=0
0,05 mol
0,06 mol
0
0
en cours
0,05- x
0,06 - x
x
x
final
0,05-0,02 = 0,03 mol
0
2*0,02 =0,04 mol
3*0,02=0,06 mol
avancement maximal : l'un au moins des réactifs a disparu
soit 0,05-x =0 --> x=0,05 mol
soit 0,06-3x = 0 --> x=0,02 mol
on retient la plus petite valeur: elle correspond à l'avancement maximal
C2H6O est en excès et la réaction s'arrète lorsque tout O2 est consommé.
la composition finale du mélange est donnée par la dernière ligne du tableau.


4étude graphique
Le graphe ci dessous représente l'évolution, en fonction de l'avancement de la réaction x, des quantités de matière des réactifs et des produits d'une réaction se produisant dans le haut fourneau. Les réactifs sont la magnétite Fe3O4, le monoxyde de carbone CO; les produits sont le fer et le dioxyde de carbone.
  1. Ecrire l'équation de cette réaction en utilisant les nombres stoechiométriques entiers les plus petits possibles .
  2. Comparer le nombre stoéchiomètrique de chaque espèce et le coefficient directeur de la droite correspondante.
  3. A partir du graphe déterminer:
    l'avancement maximal de la réaction et le réactif limitant
    la composition (mol) de l'état initial et de l'état final.
courbe (1) : CO ; courbe (2) : magnétite ; courbe(3) : CO2) ; courbe (4) : Fe
corrigé
Fe3O4 CO donne 3 Fe + 4 CO2coefficient directeur

de même pour les autres droites : (2) donne -1 / 1 = -1
(3) donne : 3 / 0,75 = 4 ; (4) donne : 3/1 = 3
les valeurs absolues des coefficients directeurs correspondent aux nombres stoéchiométriques.
composition initiale :
produits : 0 mol
réactifs :

composition finale :

CO : entirement consommé : l'avancement maximale correspond à 0,75 mol


4Fe(OH)3
A 4,0 mL de solution de chlorure de fer (III) ( [Fe3+] =0,10 mol.L-1 ), on ajoute 8,0 mL de solution de soude ([OH- ]= 0,70 mol.L-1 ) .Les ions Fe3+ réagissent avec les ions OH- pour donner un précipité d'hydroxyde de fer (III).
  1. Ecrire l'équation de la réaction .
  2. Quelles sont , à l'état initial , les quantités d'ions Fe3+ et OH- ?
  3. Etablir le tableau traduisant l'état du système lorsque x mol d'ions fer (III) ont réagi .
  4. Quel est l'avancement maximal? En déduire les quantités de matière des différentes espèces intervenant dans la réaction à l'état final .
  5. Quelles sont les concentrations des ions Fe3+ et OH- à la fin de la réaction ?


corrigé
Fe3+ + 3 HO- donne Fe(OH)3 solide rouilleconcentration (mol /L) fois volume (L) = quantité de matière (mol)
initial : Fe3+ : 4 * 0,1 = 0,4 mmol ou 4 10-4 mol
HO- : 8* 0,7 = 5,6 mmol
Fe3+
HO-
Fe(OH)3
initial t = 0
0,4 mmol
5,6 mmol
0
en cours
0,4- x
5,6 - x
x
final
0
5,6- 3*0,4 = 4,4 mmol
0,4 mmol
avancement maximal : l'un au moins des réactifs a disparu
soit 5,6 - x =0 --> x=1,86 mmol
soit 0,4- x = 0 --> x=0,4 mmol
on retient la plus petite valeur: elle correspond à l'avancement maximal
HOest en excès et la réaction s'arrète lorsque tout Fe3+ est consommé.
la composition finale du mélange est donnée par la dernière ligne du tableau.
concentrations : diviser par le volume total : 12 mL
[HO-]= 4,4 / 12 = 0,366 mol/ L
et zéro pour l'ion fer III


5AlCl3
On veut obtenir 10g de trichlorure d’aluminium à partir d’aluminium et de dichlore.
Quelle masse d’aluminium et volume de dichlore doit-on prendre au minimum au départ ?
Al=27 ; Cl=35 g/mol ; volume molaire : 24 L/mol

corrigé
Al +1,5 Cl2= AlCl3
masse molaire trichlorure d'aluminium : 27+3*35,5 = 133,5 g/mol
masse (g) / masse molaire (g/mol) = 10/133,5=0,075 mol AlCl3.
conditions stoéchiométriques :
donc 0,075 mol Al : 0,075*27= 2g.
donc 1,5*0,075 = 0,112 mol Cl2 :
volume molaire (gaz) * Qté de matière (mol) = 0,112*24 = 2,7L.


6Fe2O3
On prend 8g de fer et 1,8L de dioxygène pour obtenir l’oxyde de fer III.
Déterminer le réactif limitant ? Quelle masse d’oxyde de fer obtient-on ?
Fe = 56 ; O=16 g/mol ; volume molaire : 24 L/mol

corrigé
2Fe
+1,5O2
=Fe2O3
iniital
8 /56 = 0,143 mol
1,8/24 = 0,075 mol
0
en cours
0,143-2x
0,075-1,5 x
x
fin
0,143-2*0,05= 0,043 mol
0 (en défaut)
0,05 mol
0,075-1,5 xmax=0 soit : xmax= 0,05 mol.0,143-2xmax=0 soit xmax= 0,072 mol
masse d'oxyde : Qté de matière (mol) * masse molaire (g/mol) = 0,05*(2*56+3*16)= 8g.
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